There is considerable scientific evidence that molecular hydrogen has many health benefits. Check out this presentation by Tyler LeBaron (Founder of the Molecular Hydrogen Foundation):
I am currently consuming molecular hydrogen infused drinking water everyday as part of my PieEconomics diet.
Stores do not carry this type of drinking water because the infused hydrogen molecules escape from the surrounding water molecules within a day or so, even if the storage container is tightly sealed.
Simple DIY instructions achieving high H2 concentrations using low cost off-the-shelf materials:
List Of Materials:
One set of five Magnesium Element Metal Rods Ingot High Purity 99.995%, 3-11/16" long x 5/8" diameter. $20.95 ($15.00 + $5.95 shipping). You won't have to reorder for several years.
Malic Acid 1 Lb Pack FCC/ USP/ Food Grade. Ebay, $10.00 with free shipping.
Measuring Spoon (oval shaped): 1/4 teaspoon or 1 gram; perhaps from a set like this:
Stainless Steel Mini Measuring Spoons. Amazon, $5.96 with free shipping on eligible orders.
Test Tube with Cork Stopper. Combine as a single order from Lake Charles Mfg.:
Test Tubes, 20x150mm, Borosilicate Glass, Round Btm. You only need one but they come in a Pack of 10 (minimum quantity orderable) for $1.72 total plus shipping.
Cork Stoppers, size 7, quality XX (good). You only need one but they come in a Pack of 25 (minimum quantity orderable) for $5.24 total plus shipping.
Shipping can be combined on the Test Tubes and the Stoppers. Subtotal Test Tubes plus Stoppers = $6.96. Shipping to my location was $11.83, so I would pay $18.79 total.
2mm Surgical Steel Piercing Needle. Ebay. You only need one but they come in a Pack of 10 (minimum quantity orderable) for US $85 cents total (US 77 cents + US 8 cents shipping) from China.
Straw, 12 inch long, perhaps part of this pair:
Milkshake Straws, Extra-long Stainless Steel, 12 Inches Long. Amazon, $5.39 with free shipping.
Powerade plastic bottle, 20 oz., empty, less than $2. The 32 oz. size also works (see comment section below) but I prefer to drink the entire contents at one time which the 20 oz. size is better suited for.
Dental Lab Vibrator, Ebay. $45.15 with free shipping.
Filtered Water, refrigerated.
The basic design is that a vented stoppered test tube is placed inside a plastic water bottle. A chemical reaction that takes place inside the test tube vents gas which, together with the pressure created, infuses the bottle's drinking water with hydrogen. Most of the reactants remain inside the test tube while brewing and shaking, after which the test tube's contents are disposed of (except for the magnesium rod which is retrieved for later reuse).
Preparing the cork:
The cork stopper needs to allow for proper venting of the hydrogen gas from the test tube, while at the same time not letting any of the water surrounding outside the test tube in. Let's read how cork quality affects venting, from the website of a company that sells higher quality cork: "Cork Stoppers manufactured from 100% natural cork harvested in Portugal. The quality of the Cork Stoppers is measured by the lenticels (small crevices that occur in all natural cork). The fewer the lenticels, the higher the grade of cork... If sealing dry goods and solids (sand or salt, for example), a XXX Standard Grade will do the job. If sealing liquids where more secure seal is important, we recommend XXXX Premium Grade."
For our application the lower quality cork is appropriate, since it is desirable for bubbles to escape the test tube by working their way through irregularities in the cork. The lower XX quality cork we are using (note that all qualities are food grade) allows for venting while higher quality cork might not.
The irregularities in cork sometimes tend to reseal. That is the nature of cork. The hollow piercing needle should help the pressure between the test tube and the bottle stabilize more quickly. Push the needle vertically into the top of the cork, with the sharp side slightly protruding the bottom of the cork. Retract the needle slightly so that the sharp tip is slightly recessed for safety reasons. The dull side will protrude from the top of the cork by about an inch (the needle is 2 inches in length). Use an ordinary pin to push out any pieces of cork that may be stuck inside the piercing needle. Sterilize and condition the cork initially and once a month thereafter, as follows: Bring a couple inches of water to boil in a saucepan. Turn off the heat, and then place the cork (including needle) in the pan, and cover. Remove cork after 2 to 2-1/2 minutes.
Preliminary bottle preparation:
Fill the bottle with refrigerated filtered water near full, and pour off about a half cup into a drinking glass. Place the open bottle and the drinking glass next to the sink.
Preparing the test tube:
Put approximately one gram or one-quarter teaspoon of malic acid powder into the test tube. Tip the test tube and slowly slide a half size magnesium rod down the side of the test tube. If the rod is narrow due to months of use, place the widest/ dullest side facing down, to reduce chance of test tube breakage.
Hold the test tube in one hand, and with your other hand carefully pour a small amount of water from the drinking glass into the test tube, so that the liquid level is about a half inch lower than the top of the test tube. I used to use a funnel, but with a little practice it is easier not to. If you pour too much water into the test tube quickly pour some off into the sink.
Stopper the test tube with the vented cork. Twist the stopper gently (to reduce chance of test tube breakage) but firmly until less than half an inch of the cork is inside the test tube. There should be very little space between the bottom of the cork and the surface of the water in the test tube. When brand new, the cork won't go in as easily as it will after it's initial conditioning (boiling). After numerous brews it becomes even easier to work with, and still works fine even after showing lots of wear.
Finishing with the bottle:
Once the test tube has been prepared you must act quickly so you don't waste too much of the hydrogen gas that is now escaping. Holding the bottle at approximately a 45 degree angle over the sink, tilt the stoppered test tube allowing it to gently slide all the way down along the bottle's inner wall. Place the open bottle next to the sink and fill the bottle up the rest of the way with water from the drinking glass. The water should have a convex surface. As you tightly screw on the cap (use a washcloth to get a good grip and to protect fingers from the serrated cap) there should be a slight overflow. Place the bottle into the freezer until traces of ice are just starting to form. For my freezer I currently use 32 minutes. Definitely use a kitchen timer or a free online timer. Caution: Do not go much past thirty minutes in the freezer, or the bottle may become permanently damaged.
After removing the bottle from the freezer, the bottle must be agitated before opening it, to speed up hydrogen production and melting of ice crystals. Agitate the bottle for 20 minutes on the dental lab vibrator, followed by one minute of agitation by hand.
To use the dental lab vibrator, stabilize the bottle on the platform using two belts. This lets me run the machine unattended (while nearby). The belts go under the machine and over the top of the bottle. The machine has four rubber feet. Lay the two belts under the machine so that the first belt passes under the left back foot and under the right front foot, and the second belt passes under the right back foot and under the left front foot. Using cloth belts of the type that have two metal rings make tightening the belts easier. Do not tighten too much, or agitation will be reduced. Tie a string around the circumference of the bottle (about 3 inches up from the bottom of the bottle) to hold the belts in place against the bottle. A thick shoelace works well for this purpose, securing using a single knot and then a bow. Now, if you place the machine on an empty upside-down cardboard shipping box (perhaps the box the machine was shipped in), the machine while turned on tilts very slightly in numerous directions, greatly magnifying the vibration. Vibrate it at about 50% of top speed (just enough speed that the test tube begins moving around but not enough speed to cause test tube breakage), for 20 minutes. The jostling test tube acts like a magnetic stirrer.
After taking the bottle off of the dental lab vibrator, continue vibrating the bottle by hand, as follows: Sit with your elbows resting on a table, and hold the bottle horizontally with one hand on the base of the bottle and one hand over the cap and neck. Shake the bottle toward and away from you, while at the same time moving your thumbs upward to spin the bottle on its axis. This approach greatly increases the surface area of the water that the H2 gas initially touches, and constantly folds the surface area into the rest of the water dispersing the H2 more evenly throughout the water. Less than an inch of the test tube's solution escapes the test tube into the drink. I find this small amount of seepage tolerable (and as explained below, this magnesium malate seepage has added health benefits).
Do not open the bottle until you are ready to drink it. After opening the bottle (use a washcloth to get a good grip and to protect fingers from the serrated cap) do not try to capture and breathe the escaping hydrogen gas. Some of the magnesium compound by-product vaporizes and mixes in with the hydrogen gas escaping from the test tube, so what escapes upon opening the bottle can be somewhat caustic* if collected and breathed.
*I don't mix lime (or lemon) juice in with the drinking water in the bottle, since this seems to amplify that effect.
Very rarely will the test tube have broken while in the bottle. This most likely would be a result of not having followed the precautions mentioned above. (For example, from not tipping the test tube enough when loading the magnesium rod or from not tipping the bottle enough when loading the test tube, or from trying to push the cork in too far). Caution: Upon opening the bottle, inspect the test tube carefully and if there are any signs of breakage, do not drink the bottle's water. If you are inexperienced, consider pouring the bottle's contents into a drinking container, catching the test tube with your hand, to better inspect for breakage before drinking. Care also needs to be taken not to drop the test tube when handling it outside the bottle.
I find that using a straw works well for quickly drinking the hydrogen water from the bottle. My 8 inch glass straw is too short, so I recommend the 12 inch long food grade stainless steel milkshake straw, that has the added advantage of being unbreakable.
After you have finished drinking, carefully tip the bottle until the test tube slides out. Rinse all items, including the magnesium rod. After quickly rinsing the rod with water, shake off the excess water and then let it air dry. Do not delay removing, rinsing and drying the magnesium rod; you need to stop the chemical reaction as soon as possible to preserve the rod for future use.
The four factors affecting hydrogen concentration (as distinguished from hydrogen production) are: Pressure (more is better), Temperature (near freezing is best), Agitation, and Quantity of Hydrogen Gas (beyond some minimum amount, only helps to the extent that it is needed to: 1. increase pressure, and 2. increase the size of the hydrogen gas pocket aiding effectiveness of agitation).
The plastic bottle expands nicely making room for a good amount of hydrogen gas to collect below the cap while also allowing lots of pressure to build up. It was using plastic bottles that two scientists separately verified achieving 5 ppm (parts per million) or more of hydrogen concentration.
The first scientist, who comments using the name Hip, performed shaking and vibration testing using a plastic bottle, and stated: "when you don't shake the bottle, you only get 1 ppm concentration (even though the internal pressure in the bottle is 6 atmospheres); but after just 30 seconds of vigorous shaking, you get 5 ppm."
In an earlier post he stated: "In terms of whether increased shaking and agitation of the water in the bottle produces higher concentrations of dissolved hydrogen, I can confirm that it definitely does. I have an electric muscle massager device (called a Thumper®) which, produces strong mechanical vibrations. I used this Thumper massager to vigorously agitate for 15 minutes the water in my 1.5 liter bottle... When I then tested the H2 concentration of the water after this vigorous agitation, it was 7.7 ppm."
The second scientist, who uses the name PH2W in the comments below, emailed: "I was able to replicate Hip's method using a plastic soda bottle, but with using your glass test tubes and corks, achieving 5+ ppm of H2 verified by using the H2Blue drops..." (Note: The H2Blue method of measuring the ppm concentration of H2 in water is explained in Glen Ingram's video, below.) ... "So far I have not found a difference in concentration between shaking by hand for 30 seconds and any amount of time on the dental vibrator; I am still running more tests on this particular variable to be sure but so far there has been no difference. I know Hip had a noticeable difference in his concentration, but I'm curious if it is due to one of two different possibilities: 1. It made a difference since he uses plastic or 2. It was only a transient concentration difference due to restarting the reaction with the intense shaking but not actually dissolving more hydrogen." Note that PH2W now uses and does testing with a metal bottle (see below) so that may very well explain why he is not seeing higher hydrogen concentrations using the vibrator. There is less bottle expansion with a metal bottle, allowing less of a hydrogen pocket to form and perhaps limiting hydrogen infusion whichever method of agitation is used.
PH2W makes a good point about transient concentration. Hydrogen bubbles move toward and collect at the top, so if H2Blue testing is done using the topmost part of the water, it will register much higher hydrogen concentration than what would be measured using the vast majority of the water in the bottle. To get a more accurate reading, PH2W now pours out most of the water, waits two hours, and then tests the water remaining in the very bottom of the bottle. Since hydrogen infused in water has a half life of two hours, he takes the reading and doubles it. This results in a very conservative reading, such that PH2W's value of 3.4 ppm using a metal bottle may actually be on par with his value of 5+ ppm that he earlier measured using the plastic bottle that may have included transient hydrogen.
My blog used to specify the lesser agitation methods used by these two scientists. A commentator to this blog (see below) claimed he was not achieving the H2 concentrations that these two scientists were getting using a bottle like mine, so that is why I am now using the dental lab vibrator for a full 20 minutes, followed by hand agitation (shaking and spinning) for at least an additional minute.
Are plastic bottles food grade?
Powerade bottles are comprised of PET (or PETE) plastic, which is generally considered safe.
It was PH2W, however, who brought to my attention some lingering concerns about its safety based on these studies:
And here is a newer study: https://www.sciencedaily.com/releases/2018/09/180913113940.htm
As a result, I experimented with using a food grade stainless steel bottle, although I have gone back to using the plastic Powerade bottle as described above, as of early May, 2017.
Previous method (March 2017 thru May 2017) -- Using a stainless steel bottle:
This method substitutes the following items for the Powerade bottle listed above:
Klean Kanteen stainless steel water bottle, 27 ounce single walled. Ebay, $12.37 with free shipping. (At least $5 more if you want one without a painted exterior design.)
Klean Kanteen classic all stainless steel loop cap, Amazon, $9.10 with free shipping on eligible orders.
(Avoid purchasing the Klean Kanteen Flip Loc Cap, which is not screw on and does not seal as well.)
Other recommended supplies: A small (baby's?) sock, and (2) Rubber Bands (Wide, like the type used for bunching broccoli).
The directions are similar to when using the plastic bottle, with these differences:
The plastic cap that comes with the Klean Kanteen bottle is useless for our purpose since it is hollow and unavoidably traps a large pocket of air upon closing. The metal cap has a solid bottom surface that protrudes well into the bottle, leaving no air pocket.
To aid in gripping the bottle and cap, put one wide rubber band around the cap and the other wide rubber band around the wide part of the bottle. These rubber bands do not have to be removed between brews.
Capping the bottle: Unlike when using plastic bottles, stainless steel bottles don't allow for much bottle expansion. The hydrogen gas has to go somewhere, so when the metal bottle is filled up all the way with water leaving no air pocket, space for the gas initially comes from compression of the water. Liquids, however, can't be compressed very much, so the gas will push out any concave portion of the bottle so that it becomes convex. The bottom of my Klean Kanteen bottle is concave, but hydrogen production makes the bottom convex, causing the bottle to tilt slightly (although not fall over). This allows a larger hydrogen gas pocket to form at the top. When I eventually take off the top, the bottom immediately retracts back into its original concave position (sometimes it needs a nudge).
Grip the bottle and the cap where the rubber bands are (gripping the cap's rubber band using a wash cloth provides even greater leverage). Screw on the cap as tightly as you can in one motion (do not repeat). Place the small sock over the top and extend it down the body of the bottle at least past the bottle's rubber band. This tethers the cap in case it pops out. Keep your face away from the opening of a pressurized metal bottle.
Uncapping the bottle: It is much more difficult to open a metal bottle than to open a plastic bottle after it has been in the freezer. For a metal bottle you may need something more than just rubber bands to use as a grip... possibly a rubber mat. PH2W uses a metal vise together with a metal clamp grip.
If you leave the bottle in the freezer for much longer than 30 minutes, the cap pushes out of the bottle (sliding past the groves) by about a half inch, embedded in ice. The bottom of the metal bottle, which had been concave, becomes permanently convex making it difficult or impossible to sit in an upright position. On the next brew using this permanently expanded bottle, during shaking the cap might shoot straight out, possibly hitting the wall or ceiling if not causing bodily injury.
Unlike when using a plastic bottle, the cork usually comes off the test tube too early, spilling reactants into the drinking water. If this were to happen when using the metal (or even a plastic) bottle, drink the water in the bottle anyway since it is beneficial to do so (see below) and you won't notice any side effects from only occasionally drinking some of the magnesium byproduct.
Regarding the stainless steel bottle, PH2W emailed: "...all in all I am very excited about having 3.4 ppm produced with all food grade products in stainless steel, especially with still having the potential to increase that concentration." (Note: While the magnesium rods are 99.995% pure, and any impurities would mostly be confined to the water in the test tube, they have not been certified as food grade.)
PH2W's latest emails indicated that after many different setups using a metal bottle his testing has not exceeded 3.4 ppm concentration. I have weighed the difficulties using a metal bottle along with the inability to increase hydrogen concentration using metal, with the lingering concerns of using plastic, and have decided to go back to using the plastic bottle. Not only is PET (or PETE) plastic generally considered safe, but the water is only in the bottle for 53 minutes. Contrast this with store bought beverages which are typically in the bottle for weeks or months. I believe the test tube method is optimized using a plastic bottle.
Original Method (October 2016 thru December 2016) -- Using a glass bottle with a flip top cap, and no test tube:
Glen Ingram demonstrated this simple method:
I originally titled this blog page Hydrogen Drinking Water 3.0 because according to Glen, these brewing parameters have been consistently producing 3.0+ parts per million (ppm) of molecular hydrogen concentration in water. That is five times the concentration of the best water ionizing machines, which max out at 0.6 ppm molecular hydrogen when producing 9.5 pH water. I discontinued using this method for these reasons:
1. Impurities and laxative effect:
With this method the brewing bottle is the reactor, and the water in the reactor contains residue from the magnesium and malic acid, as well as magnesium malate and magnesium hydroxide byproducts, all of which you end up drinking along with the hydrogen infused water.
Here is what Glen had to say about the purity rating of 4N 99.99% for his magnesium rods manufactured in Hong Kong by MGA: "I had one of my brews tested by a lab several months ago to satisfy myself that there were no heavy metals in the rods I was using and they came out fine...no lead or other bad stuff at all." Having your own testing done is a good idea, as there are no magnesium rods that have been certified as food grade, so far as I know. While I have used Glen's source for magnesium rods, the source I now specify lists a slightly better purity rating of 99.995%.
The residues from the magnesium and malic acid are generally good for you:
Magnesium is a mineral that's crucial to the body's function.
Malic acid is a component of almost all fruits, and is beneficial to ingest.
Magnesium malate tops the list of recommendations for easing pain and fatigue, especially for those with fibromyalgia.
As for the residue of magnesium hydroxide, commonly known as milk of magnesia, in sufficient quantities it can act as an antacid and laxative, as do most magnesium related compounds.
An important part of my PieEconomics diet are healthy fats (avocado, coconut, mackerel, flax seed, walnuts, organic chicken, organic eggs, organic cheese, grass fed beef), as well as magnesium rich green vegetables. Adding too much more magnesium and related byproducts to this diet can have a laxative effect and is not a good idea.
Exposing drinking water to four full size magnesium rods and byproducts is much more severe than the one magnesium rod (which is also shorter in length) and byproducts which are largely contained using the test tube method. However, any of the small amount of magnesium and related byproducts that seep from the test tube into my drinking water I am actually grateful for.
2. The concentration of hydrogen is limited to 3 ppm, since using glass pop bottles automatically leak some of the contents when the pressure builds up too much, to prevent glass from shattering.
3. The water needs to be boiled to accelerate hydrogen production. The reactants are not concentrated together as they are when confined to a test tube, where hydrogen production is vigorous even in chilled water.
4. Total brewing time is 3+ hours instead of the shorter 52 minutes using the test tube method. Water which starts out boiling takes much longer to cool. Hydrogen concentration (as distinguished from hydrogen production) increases in proportion to the coldness of water, and is optimal with water that is near freezing.
5. Even accounting for the tube, less water is displaced using the test tube method, leaving more water for drinking.
Brown's Gas- contains hydrogen gas as a by-product:
At least one employer and perhaps some bars offer brown's gas infused water (which contains hydrogen gas as a by-product) for immediate consumption by their employees/ patrons. Here is a $19,000 device that dispenses such water:
This device starts with water, and with the use of electricity and catalysts outputs Brown's gas (also called HHO) which is an electrified form of water that has many interesting uses. The primary use is as a pollution-free fuel, whose only exhaust is water. This same gas that can be used to fuel energy saving devices for motor vehicles, and to fuel torches, can after filtering be used to benefit one's heath in three ways: (1) surrounding a part of the body with it to treat conditions such as carpal tunnel syndrome, (2) infusing it into drinking water, or (3) inhaling it.
I first found out about the health benefits of molecular hydrogen from George Wiseman. When I was writing articles on water cavitation, I became familiar with his company, Eagle-Research.
George believes it is not just the hydrogen gas by-product, but also the HHO molecules themselves that provide a health benefit. He displays studies showing growth in plants and in fish using HHO (with H2) infused water vs. non-infused water, but we also have to compare these with plants and fish using H2 only infused water.
The brown's gas (including hydrogen gas by-product) can be bubbled through drinking water to produce hydrogen infused water within about ten minutes. Unfortunately, the vessel cannot be easily pressurized, so maximum hydrogen concentration in the drinking water is limited to only about 1.57 ppm.
The gas (which can easily be adapted for use as an HHO torch) can be emitted at a slower rate, allowing safe inhalation of hydrogen diluted with air. There are added benefits to getting the hydrogen via drinking water rather than by breathing it, however, as explained by Hip:
"One thing that breathing H2 gas cannot do, but hydrogen rich water does do, is induce ghrelin release. Ghrelin has mood boosting, antidepressant properties, as well as cognitive enhancing and neuroprotective effects, and I think ghrelin release is most likely responsible for the mood boost that I experience within an hour or two of drinking 500 ml of 5 ppm hydrogen rich water."
Pills that create H2 nano bubble clouds:
Look at the videos for three different brands of this new form of molecular hydrogen:
All three brands create H2 water with H2 concentration in excess of 9 PPM after about 2 minutes at room temperature in an open glass. During that time, H2 nano bubbles form a cloud, first at the top of the glass, and then spreading down throughout the glass, achieving uniform distribution.
Posts by H2enthusiast answer some of our questions:
What's going on here, since we know that PPM cannot exceed about 1.57 without pressurization? "The nano bubbles aren't saturated/dissolved. As Hip said, and has been pointed out many times, that is impossible without external pressurization. That being said the quasi dissolved H2 is present in solution, at very high levels... Hip brought up that the quasi dissolved gas may be similar to saturated gas but we do not know, and that is correct. That being said there are no human comparative studies."
Can this effect be easily duplicated using DIY methods? "To make the cloud relies on tightly controlled particle shapes and sizes of all of the ingredients, as well as compression force for time release. The reaction and dissolution kinetics need to be dialed in to create that cloud. It isn't something that can be achieved on household equipment."
The costs are at least a dollar per pill. While the test tube in a bottle does not achieve quite as much PPM concentration, it is vastly less expensive than using pills. I might consider using the pills for when I'm traveling.-----
Check with your physician to see if these types of hydrogen infused waters are OK for you to drink.
I am a novice so please do your own research.